To Russia with Love examines human rights through the lens of LGBT athletes, with American athlete and commentator Johnny Weir serving as the viewers' guide.
| Actor | Role |
|---|---|
 Jane LynchSelf - Narrator (voice) | Self - Narrator (voice) |
 Martina NavratilovaSelf - Tennis Icon | Self - Tennis Icon |
| JJason CollinsSelf - First Openly Gay NBA Player | Self - First Openly Gay NBA Player |
 Johnny WeirSelf - Olympic Figure Skater | Self - Olympic Figure Skater |
 Ban Ki-moonSelf - Secretary General of the United Nations | Self - Secretary General of the United Nations |