British Ministry agent John Steed, under direction from "Mother", investigates a diabolical plot by arch-villain Sir August de Wynter to rule the world with his weather control machine. Steed investigates the beautiful Doctor Mrs. Emma Peel, the only suspect, but simultaneously falls for her and joins forces with her to combat Sir August.
| Actor | Role |
|---|---|
 Ralph FiennesJohn Steed | John Steed |
 Uma ThurmanEmma Peel | Emma Peel |
 Sean ConnerySir August de Wynter | Sir August de Wynter |
 Patrick MacneeInvisible Jones (voice) | Invisible Jones (voice) |
 Jim BroadbentMother | Mother |
 Fiona ShawFather | Father |
 Suzy Eddie IzzardBailey | Bailey |
 Eileen AtkinsAlice | Alice |
 John WoodTrubshaw | Trubshaw |
 Carmen EjogoBrenda | Brenda |
 Keeley HawesTamara | Tamara |
 Shaun RyderDonavan | Donavan |
 Nicholas WoodesonDr. Darling | Dr. Darling |
| MMichael GodleyButler | Butler |
 Richard LumsdenBoodle's Porter | Boodle's Porter |
| SSolly AssaBob | Bob |
 Nadim SawalhaWorld Council of Ministers | World Council of Ministers |
 Christopher GodwinWorld Council of Ministers | World Council of Ministers |
 David WebberWorld Council of Ministers | World Council of Ministers |
 Roger Lloyd PackProfessor | Professor |