Love Is Not All Around explores modern relationships, interweaving the love stories of the six characters to reveal what love means to young people in metropolitan Hong Kong.
| Actor | Role |
|---|---|
 Stephy Tang Lai-YanBo | Bo |
 Sammy LeungWing | Wing |
 Alex Fong Lik-SunRyan | Ryan |
 Miki Yeung Oi-GanMon | Mon |
 Hins Cheung King-HinJoe | Joe |
 Philip Ng Wan-LungMichael | Michael |
 Janice Man Wing-SanRyan's ex-girlfriend | Ryan's ex-girlfriend |
 Angela Au Man-SzeJoyce | Joyce |
| TTerry WuSiu-mo | Siu-mo |
| WWang YibingBik-lin | Bik-lin |
 Monie Tung Man-LeeMary | Mary |
| CCindy LeeSally | Sally |
 Leanne Foo Hiu-MeiSingle Dating Party's participant | Single Dating Party's participant |
 Sheila Chan Suk-LanNot listed | Not listed |
 Kary Ng Yu-FeiNot listed | Not listed |
 Linda Chung Ka-YanNot listed | Not listed |
 Mimi Chu Mai-MaiNot listed | Not listed |
 Mimi Kung Chi-YanNot listed | Not listed |