Archive footage of interviews, concerts and personal material bring to light the solo performance work of Mercury, the lead singer of Queen.
| Actor | Role |
|---|---|
 Freddie MercurySelf (archive footage) | Self (archive footage) |
 Roger TaylorSelf | Self |
 Brian MaySelf | Self |
 Luciano PavarottiSelf (archive footage) | Self (archive footage) |
 Montserrat CaballéSelf | Self |
| PPeter FreestoneSelf | Self |
 David ArnoldSelf | Self |
 John ReidNot listed | Not listed |
 Matt LucasNot listed | Not listed |
| DDavid WiggNot listed | Not listed |
| JJim HuttonSelf (archive footage) | Self (archive footage) |
| DDavid RichardsNot listed | Not listed |
 Jim BeachNot listed | Not listed |