Through vintage film clips of past Bond movie epics, and with the participation of several former "Bond Girls" as interviewees (among them Dr. No's Ursula Andress and Diamonds Are Forever's Jill St. John), the documentary traces the evolution of the typical James Bond heroine from decorative damsel in distress to gutsy (but still decorative) participant in the action.
| Actor | Role |
|---|---|
 Maryam D'AboHerself / Interviewer | Herself / Interviewer |
 Ursula AndressHerself | Herself |
 Honor BlackmanHerself | Herself |
 Luciana PaluzziHerself | Herself |
 Jill St. JohnHerself | Herself |
 Jane SeymourHerself | Herself |
 Maud AdamsHerself | Herself |
 Lois ChilesHerself | Herself |
 Carey LowellHerself | Herself |
 Judi DenchHerself | Herself |
 Michelle YeohHerself | Herself |
 Halle BerryHerself | Herself |
 Rosamund PikeHerself | Herself |