"Chile On Hell" was filmed at the Teatro Caupolican in Santiago, Chile on May 10, 2013, and features Anthrax - Joey Belladonna/vocals, Scott Ian/guitar, Charlie Benante/drums, Frank Bello/bass and Jon Donais/lead guitar. The band performed an extended set that featured songs from Anthrax's entire catalogue - all the fan-favorites including "I Am The Law," "Indians," "Madhouse," "Caught In A Mosh," "The Devil You Know," and "I'm Alive." "Santiago was the perfect place to film the show for this," said Anthrax's Charlie Benante. "When we'd played there in the past, we'd finish our set, play our encore and go back to the dressing room. But every time, the fans would continue to scream and cheer and clap. I mean, they went on and on, they wouldn't stop. One time Scott and I walked out to the side of the stage just to watch what was going on in the audience, it was intense. Why wouldn't we want to film a DVD in front of an audience like that?
| Actor | Role |
|---|---|
 Joey BelladonnaVocals | Vocals |
 Frank BelloBass | Bass |
 Scott IanGuitars | Guitars |
 Charlie BenanteDrums | Drums |
| JJonathan DonaisGuitars | Guitars |